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    3. 酯氨解反应催化剂 – LiTFSI(LiNTf2)双三氟甲烷磺酰亚胺锂

      This post is part of the series LiTFSI - 应用

      Other posts in this series:

      1. 酯氨解反应催化剂 – LiTFSI(LiNTf2)双三氟甲烷磺酰亚胺锂 (Current)
      2. 环氧开环反应催化剂 – LiNTf2(LiTFSI)双三氟甲烷磺酰亚胺锂

      咨询LiTFSI,可联系默尼化工科技(上海)有限公司,www.ilschemcn

       

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      LiNTf2-Catalyzed Aminolysis of Lactones with Stoichiometric Quantities of Amines

      Abstract: LiNTf2 in the reaction of lactones with amines is able to
      activate cyclic esters towards ring opening, thus leading to clean
      open-chain amides under mild conditions and using a stoichiometric
      amount of amine. The generality of the method was demonstrated
      by a range of selected lactones and amines.
      Key words: amides, ring opening, Lewis acids, lactones, catalysis

       

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